[1]李志.废旧轮胎裂解油加氢装置的汽提工艺方案比较[J].石化技术与应用,2024,6:460-464.
MA Zhi-yuan,WANG Hui,TIAN Qiao-qiao.Industrial application and calibration of LC-6 type gasoline olefins reduction catalystin heavy oil catalytic cracking unit[J].Petrochemical technology & application,2024,6:460-464.
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废旧轮胎裂解油加氢装置的汽提工艺方案比较(PDF)
MA Zhi-yuan,WANG Hui,TIAN Qiao-qiao.Industrial application and calibration of LC-6 type gasoline olefins reduction catalystin heavy oil catalytic cracking unit[J].Petrochemical technology & application,2024,6:460-464.
《石化技术与应用》[ISSN:1009-0046/CN:62-1138/TQ]
- 期数:
- 2024年6期
- 页码:
- 460-464
- 栏目:
- 出版日期:
- 2024-11-10
文章信息/Info
- Title:
- Industrial application and calibration of LC-6 type gasoline olefins reduction catalystin heavy oil catalytic cracking unit
- 文章编号:
- 1009-0045（2024）06-0460-05
- 作者:
- 李志
- 上海润和科华工程设计有限公司，上海200120
- Author(s):
- MA Zhi-yuan; WANG Hui; TIAN Qiao-qiao
- ZhongJie Petrochemicals Co Ltd，CNOOC，Cangzhou 061101，China
- Keywords:
- heavy oil catalytic cracking (RFCC); gasoline olefin reduction catalyst; diesel yield; propylene
- 分类号:
- TE 992.3
- DOI:
- 10.19909/j.cnki.ISSN1009-0045.2024.06.0460
- 文献标识码:
- B
- 摘要:
- 使用Aspen Plus模拟软件对33万t/a废旧轮胎裂解油加氢装置的2种汽提工艺方案（双塔方案和单塔方案）进行对比，并讨论了热、冷低分油温度（Th，Tc）以及汽提蒸汽（1.0 MPa，250 ℃）总耗用量（mst）对硫化氢脱除效果及汽提塔塔底流出物收率（Y）的影响。结果表明：在热、冷低分油进料条件均相同前提下，这2种汽提方案的塔底流出物含硫化氢量均低于10 μg/g，Y均大于93.0%；权衡考虑装置脱硫效果及能耗，选择mst为0.36 t/h较佳；单塔工艺方案优于双塔方案，前者不仅运行更加稳定、操作弹性更大，而且主要设备总投资成本仅为后者的85%，尽管其当量综合能耗比后者的高0.08 MJ/t。
- Abstract:
- In response to the quality upgrade requirements of blending components of National Ⅵ B gasoline products，the 1.2 Mt/a heavy oil catalytic cracking (RFCC) unit of CNOOC Zhongjie Petrochemical Co Ltd began to add the LC-6 type gasoline olefins reduction catalyst since October，2023，which developed by Lanzhou Chemical Research Center，PetroChina. The results showed that after using the LC-6 type gasoline olefins reduction catalyst，the volume fraction of olefins in RFCC gasoline reduced from 31% - 34% to 26% - 29%，and met the quality upgrade requirements of blending components of National Ⅵ B gasoline products and ensured the finished ex-factory gasoline products up to standard (its volume fraction of olefins not more than 15%). Compared with the blank calibration period，under the condition that the unit consumption of the LC-6 type gasoline olefins reduction catalyst reduced to 1.21 kg/t and the processing raw material was inferior heavy oil with high metal content，then the yields of dry gas，liquefied gas，gasoline，slurry and total liquid of this above RFCC unit decreased by 0.29，0.24，1.90，0.49and 0.14 percentage points，respectively. However， the yields of coke and diesel increased by 0.43 and 2.49 percentage points，respectively. Meanwhile，the volume fraction of olefins in RFCC gasoline reduced by 5 percentage points，and the volume fraction of propylene in liquefied gas increased by 1.29 percentage points.
参考文献/References
［1］ 吴晓羽，李硕，王仕峰. 废旧轮胎热裂解技术的研究进展 ［J］. 特种橡胶制品，2015，36（6）：71-75.［2］ 夏勇，阳宇，朱聪，等. 废轮胎热解过程中的动力学与热力学特性及热解油组分分析［J］.低碳化学与化工，2023，48（4）：36-44.［3］ 覃刘平，王黎. WUST 10催化下废轮胎热解反应动力学分析 ［J］. 化工环保，2021，41（4）：452-457.［4］ 许江林，孙承亮，于佳雪，等. 废旧轮胎资源化的能量与物质流分析 ［J］. 上海节能，2018（11）：850-855.［5］ 谢辉英，王婷婷，吴茶水，等. 废旧轮胎裂解油萃取脱除碱性氮的研究［J］. 精细石油化工，2020，37（6）：76-79.［6］ 刘囡南. 废轮胎裂解油品分析及深加工方案研究［J］. 中国轮胎资源综合利用，2016（10）：41-45.［7］ 黄海鹏. 加氢裂化脱硫化氢汽提塔操作优化研究［J］. 炼油技术与工程，2021，51（8）：23-26.
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2024-11-10