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《石化技术与应用》[ISSN:1009-0046/CN:62-1138/TQ]

期数:

2024年3期

页码:

233-240

栏目:

出版日期:

2024-05-10

文章信息/Info

Title:

Research progress on Ni-based composite catalytic materials for hydrogen production by sorption-enhanced steam methane reforming

文章编号:

1009-0045（2024）03-0233-08

作者:

周微; 赖晓玲*; 胡明亮; 李滨

中国海油天津化工研究设计院有限公司，天津 300131

Author(s):

ZHOU Wei; LAI Xiao-ling; HU Ming-liang; LI Bin

Tianjin Chemical Research and Design Institute Co Ltd，CNOOC，Tianjin 300131，China

关键词:

吸收强化; 甲烷水蒸气重整; Ni基复合催化材料; 制氢

Keywords:

sorption-enhanced; steam methane reforming; Ni-based composite catalytic materials; hydrogen production

分类号:

TE 624.9+1

DOI:

DOI：10.19909/j.cnki.ISSN1009-0045.2024.03.0233

文献标识码:

A

摘要:

阐述了吸收强化甲烷水蒸气重整制氢（SESMR）反应机理及其影响因素，重点从活性中心Ni，助剂（铝、镧、锆、镁、钴）掺杂和构型调整方面综述了SESMR工艺中Ni基复合催化材料的研究进展，还介绍了SESMR复合催化剂在应用中的再生、以及其他复合催化剂的研发情况。并指出：易积炭和高温烧结是Ni/CaO复合催化剂大规模应用于SESMR工艺的技术阻碍，如何降低复合催化剂在脱碳再生过程中的高温、高能耗是SESMR工艺应用的主要瓶颈，开发更加低成本、高活性、高稳定性的高效能SESMR复合催化材料是今后研究的核心。

Abstract:

The reaction mechanism and influencing factors of sorption-enhanced steam methane reforming for hydrogen production（SESMR） were described. The research progress of Ni-based composites in SESMR process was reviewed emphatically in terms of Ni active sites，doping of additives （aluminum，lanthanum，zirconium，magnesium and cobalt） and configuration adjustment. In addition，the regeneration of SESMR composite catalysts and the development of other composite catalysts were also introduced. It was pointed out that easy carbon deposition and high temperature sintering were the technical obstacles to the large-scale application of Ni/CaO composite catalyst in SESMR field. It was the main bottleneck of SESMR process application that how to reduce the high temperature and high energy consumption of composite catalysts in the process of decarbonization and regeneration. The development of the more low cost，high activity，high stability and high efficiency SESMR composite materials was the core of the future research.

参考文献/References

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备注/Memo

备注/Memo:

中国海洋石油集团有限公司CCUS重大专项基金资助项目（项目编号：KJGG-2022-12-CCUS-030403）

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更新日期/Last Update: 2024-05-10