[1]谌基国 a,张工厂 b,张彪 c,等.锂离子电池隔膜专用聚丙烯T 98系列产品的性能及其应用[J].石化技术与应用,2024,5:360-363.
SHEN Ji-guo a,ZHANG Gong-chang b,ZHANG Biao c,et al.Performance and application of special polypropylene T 98 series products for lithium ion battery separator[J].Petrochemical technology & application,2024,5:360-363.
点击复制
锂离子电池隔膜专用聚丙烯T 98系列产品的性能及其应用(PDF)
《石化技术与应用》[ISSN:1009-0046/CN:62-1138/TQ]
- 期数:
-
2024年5期
- 页码:
-
360-363
- 栏目:
-
- 出版日期:
-
2024-09-10
文章信息/Info
- Title:
-
Performance and application of special polypropylene T 98 series products for lithium ion battery separator
- 文章编号:
-
1009-0045(2024)05-0360-04
- 作者:
-
谌基国1 a; 2; 张工厂1 b; 张彪1 c; 崔晓伟1 d; 谷新华1 d
-
(1.中国石油独山子石化公司 a.研究院;b.工程管理部;c.规划和科技信息部;d.聚烯烃二部,新疆 克拉玛依 833699;2.新疆橡塑材料实验室,新疆 克拉玛依 833699)
- Author(s):
-
SHEN Ji-guo1 a; 2; ZHANG Gong-chang1 b; ZHANG Biao1 c; CUI Xiao-wei1 d; GU Xin-hua1 d
-
(1.Dushanzi Petrochemical Company ,a.Research Institute; b.Engineering Management Department;c.Planning and Science and Information Department;d.The second polyolefin Division,PetroChina,Karamay 833699,China;2.Xinjiang Laboratory of Rubber-Plastic Material,Karamay 833699,China)
-
- 关键词:
-
聚丙烯; 锂离子电池隔膜; 熔体流动速率; 氧化诱导时间; 拉伸强度
- Keywords:
-
polypropylene; lithium ion battery separator; melt flow rate; oxidation induced time; tensile strength
- 分类号:
-
TQ 325.1+4
- DOI:
-
DOI:10.19909/j.cnki.ISSN1009-0045.2024.05.0360
- 文献标识码:
-
B
- 摘要:
-
为满足国内锂离子电池隔膜专用料的市场需求,中国石油独山子石化公司采用Spheripol双环管工艺生产出锂离子电池隔膜专用聚丙烯(PP)T 98系列产品,剖析了T 98 G/T 98 F/T 98 D/T 98 CD等产品的基础性能、力学性能、热性能、相对分子质量及其分布以及隔膜制品性能。结果表明:与进口典型对标试样相比,T 98系列产品的氧化诱导时间(约38 min)较长,数均分子质量(约12.0×104)更大,相对分子质量分布(约3.1)更窄;T 98 F/T 98 G适用于干法双向拉伸工艺,T 98 D/T 98 CD适用于干法单向拉伸工艺;与进口试样制品相比,T 98 D/T 98 CD生产的锂离子电池隔膜制品透气层间极差分别降低8.8%,19.8%,纵向拉伸强度分别提高11.6%,25.4%,隔膜孔径集中度好、分布均匀、无明显双峰。
- Abstract:
-
In order to meet the domestic market demand for special materials for lithium ion battery separator, special polypropylene (PP) T 98 series products for lithium ion battery separator was produced by using Spheripol double ring tube process by Dushanzi Petrochemical Company of PetroChina. The basic properties, mechanical properties, thermal properties, relative molecular weight and its distribution of T 98 G/T 98 F/T 98 D/T 98 CD and the properties of diaphragm products were analyzed. The results showed that compared with typical imported benchmark samples, the oxidation induced time of T 98 series products(about 38 min) was longer, the number average molecular weight (about 12.0×104) was larger , and the relative molecular weight distribution (about 3.1) was narrower .T 98 F/T 98 G was suitable for dry biaxial drawing process and T 98 D/T 98 CD was suitable for dry uniaxial drawing process. Compared with imported sample products, the range between the breathable layers of the lithium ion battery separator products produced by T 98 D/T 98 CD decreased by 8.8% and 19.8% respectively, and the longitudinal tensile strength increased by 11.6% and 25.4% respectively. The separator pore size concentration was good, the distribution was uniform, and no obvious double peaks.
参考文献/References
[1] 鲁成明,虞鑫海,王丽华.国内外锂离子电池隔膜的研究进展[J].电池工业,2019,23(2):101-105.[2] 李焦丽,张成亮,梁福鑫,等.锂离子动力电池隔膜的研究及发展现状[J].中国科学,2014,44(7):1116-1124.[3] 魏文康,虞鑫海,王凯.锂离子电池隔膜的制备方法与性能[J].合成技术及应用,2018,33(4):27-30.[4] 谌基国,桑分艳,胡廷芳,等.锂离子电池隔膜专用聚丙烯的工业化开发[J].合成树脂及塑料,2018,35(4):53-56.[5] 王振华,彭代冲,孙克宁.锂离子电池隔膜材料研究进展[J].化工学报,2018,69(1):282-294.[6] Derrien G, Hassoun J, Sacchetti S, et al. Nanocomposite PEO-based polymer electrolyte using a highly porous,super acid zirconia filler[J]. Solid State Ion, 2009, 180(23/24/25):1267-1271.[7] 付莹,付传玉,张彬,等.锂离子电池隔膜专用聚丙烯生产过程的研究[J].塑料工业,2020,48(11):31-34.[8] 许德涟,李琪,乔庆东,等.高安全性锂离子电池隔膜的研究进展[J].化工新型材料,2023,51(6):40-44.
备注/Memo
- 备注/Memo:
-
中国石油独山子石化公司资助项目(项目编号:DSH 16-04)
更新日期/Last Update:
2024-09-10