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《石化技术与应用》[ISSN:1009-0046/CN:62-1138/TQ]

期数:

2025年1期

页码:

84-90

栏目:

出版日期:

2025-01-10

文章信息/Info

Title:

Research progress of H2O2 / multiphase oxidation desulfurization catalysts

文章编号:

1009-0045（2025）01-0084-07

作者:

李鹏a; 郭凯振b; 郑雨壑b; 姚红c; 刘川a

（中国石油辽阳石化公司 a.研究院；b.烯烃运行部；c.亿方公司，辽宁 辽阳 111003）

Author(s):

LI Penga; GUO Kai-zhenb; ZHENG Yu-heb; YAO Hongc; LIU Chuana

（a.Research Institute；b.Olefin Operation Department；c.Yifang Company，Liaoyang Petrochemical Company，PetroChina，Liaoyang 111003，China）

关键词:

脱硫; 氧化脱硫; H2O2; 催化剂; 离子液体; 杂多酸; 分子筛

Keywords:

desulfurization; oxidation desulfurization; H2O2; catalyst; ionic liquid; heteropolyacid; molecular sieve

分类号:

TQ 031.7；TQ 426

DOI:

DOI：10.19909/j.cnki.ISSN1009-0045.2025.01.0084

文献标识码:

A

摘要:

综述了离子液体、杂多酸杂化材料、分子筛等3类催化剂应用于 H2O2 /多相氧化脱硫体系的研究进展，包括Br?覬nsted（Lewis）酸性离子液体、以纳米管（氧化物或分子筛）为载体的负载型或金属改性的杂多酸杂化材料及 Si系（非 Si 系）分子筛催化剂等，并对比了各种催化剂的性能优缺点。指出今后的研究方向是开发比表面积大、稳定性高、成本低廉的载体材料，且基于载体制得的催化剂对燃料油中硫化合物的氧化活性高、耗氧量少、重复使用性良好。

Abstract:

The research progress of the application of ionic liquids， heteropolyacid hybrid materials and molecular sieves in H2O2 /multiphase oxidative desulfurization system was reviewed， including Br?覬nsted （Lewis） acidic ionic liquid， metal-modified or supported heteropoly acid hybrid materials with nanotubes （oxides or molecular sieves） as carriers， and Si-based （non-Si-based） molecular sieves catalysts. The advantages and disadvantages of various catalysts were compared. It was pointed out that the future research direction was to develop carrier materials with large specific surface area， high stability and low cost， and the catalysts based on the carrier had high oxidation activity for sulfur compounds in fuel oil， low oxygen consumption and good reusability.

参考文献/References

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更新日期/Last Update: 2025-01-10