[1]董鑫,蔡登定,赵泳立,等.顶空气相色谱法测定苯酚丙酮装置废水中甲基过氧化氢含量[J].石化技术与应用,2024,4:302-305.
DONG Xin,CAI Deng-ding,ZHAO Yong-li,et al.Determination of methyl hydrogen peroxide in wastewater from phenol-acetone plant by headspace gas chromatography[J].Petrochemical technology & application,2024,4:302-305.
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顶空气相色谱法测定苯酚丙酮装置废水中甲基过氧化氢含量(PDF)
DONG Xin,CAI Deng-ding,ZHAO Yong-li,et al.Determination of methyl hydrogen peroxide in wastewater from phenol-acetone plant by headspace gas chromatography[J].Petrochemical technology & application,2024,4:302-305.
《石化技术与应用》[ISSN:1009-0046/CN:62-1138/TQ]
- 期数:
- 2024年4期
- 页码:
- 302-305
- 栏目:
- 出版日期:
- 2024-07-10
文章信息/Info
- Title:
- Determination of methyl hydrogen peroxide in wastewater from phenol-acetone plant by headspace gas chromatography
- 文章编号:
- 1009-0045（2024）04-0302-04
- Author(s):
- DONG Xin; CAI Deng-ding; ZHAO Yong-li; WANG Xin
- Inspection Center of Zhejiang Petroleum & Chemical Co Ltd， Zhoushan 316000，China
- Keywords:
- headspace gas chromatography; methyl hydrogen peroxide; acetic acid; potassium iodide; methanol; derive
- 分类号:
- TQ 019
- DOI:
- DOI：10.19909/j.cnki.ISSN1009-0045.2024.04.0302
- 文献标识码:
- B
- 摘要:
- 建立了一种采用顶空气相色谱法快速测定苯酚丙酮装置废水中过氧化物的方法，其中主要过氧化物甲基过氧化氢，通过衍生化反应后测定，对该方法的准确度、精密度、重复性进行了分析。结果表明：以醋酸作为衍生化反应的酸性试剂，碘化钾水溶液质量分数为50%时，甲基过氧化氢衍生化反应最完全；在顶空平衡温度为80 ℃，顶空平衡时间为12 min时，样品含甲醇量的测定值与实际值最为接近；该方法具有较高的准确度和重复性，相对标准偏差为0.027%。
- Abstract:
- A method for rapid determination of peroxides in wastewater from phenol-acetone plant by headspace gas chromatography was established. The main peroxide， methyl hydrogen peroxide was determined by derivatization reaction. The accuracy， precision and repeatability of this method were analyzed. The results showed that the derivatization of methyl hydrogen peroxide was the most complete when the mass fraction of potassium iodide solution was 50% with acetic acid as the acid reagent. When the headspace equilibrium temperature was 80 ℃ and the headspace equilibrium time was 12 min， the measured methanol content of the sample was the closest to the actual value. The method had high accuracy and repeatability， and the relative standard deviation was 0.027%.
参考文献/References
［1］ 张广仁，王南南，彭纪铭，等.丙酮-冰醋酸在线衍生化-顶空气相色谱法测定氯唑沙宗中水合肼含量［J］.食品与药品，2020，22（3）：216-218.［2］ 於香湘，缪建军，吴鹏，等.顶空气相色谱法同时测定水中乙醛、丙烯醛和丙烯腈［J］.环境科技，2011，24（Z 1）：74-75.［3］ 中国船舶重工集团公司第718研究所.HJ 1067—2019水质 苯系物的测定 顶空/气相色谱法［S］.北京：中国环境出版集团，2020：3.［4］ 赵炳南，王苏明，王姗姗，等.GB/Z 27426—2022化学分析实验室结果有效性监控指南［S］.北京：中国标准出版社，2022：10.
备注/Memo
- 备注/Memo:
- 浙江石油化工有限公司科技开发项目（项目编号：ZSH-RD-23-101）
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更新日期/Last Update:
2024-07-10