[1]杨军朝,赵亮,王万真,等.半再生重整催化剂SR-1000氮中毒原因分析及对策[J].石化技术与应用,2023,1:55-58.
YANG Jun-zhao,ZHAO Liang,WANG Wan-zhen,et al.Analysis and countermeasures on nitrogen poisoning of semi-regenerative reforming catalyst SR-1000[J].Petrochemical technology & application,2023,1:55-58.
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半再生重整催化剂SR-1000氮中毒原因分析及对策(PDF)
YANG Jun-zhao,ZHAO Liang,WANG Wan-zhen,et al.Analysis and countermeasures on nitrogen poisoning of semi-regenerative reforming catalyst SR-1000[J].Petrochemical technology & application,2023,1:55-58.
《石化技术与应用》[ISSN:1009-0046/CN:62-1138/TQ]
- 期数:
- 2023年1期
- 页码:
- 55-58
- 栏目:
- 出版日期:
- 2023-01-10
文章信息/Info
- Title:
- Analysis and countermeasures on nitrogen poisoning of semi-regenerative reforming catalyst SR-1000
- 文章编号:
- 1009-0045（2023）01-0055-04
- Author(s):
- YANG Jun-zhao; ZHAO Liang; WANG Wan-zhen; HOU Jia-yue
- Refinery & Chemical Plant of Yumen Oilfield Company，PetroChina，Yumen 735200，China
- Keywords:
- reforming; catalyst; nitrogen poisoning; corrosion inhibitor; octane number
- 分类号:
- TE 624.9+2
- DOI:
- DOI：10.19909/j.cnki.ISSN1009-0045.2023.01.0055
- 文献标识码:
- B
- 摘要:
- 对中国石油玉门油田公司炼油化工总厂30万t/a重整装置出现的汽油辛烷值，循环气含C3，C4量下降，循环氢纯度升高等问题进行了分析，并提出了相应的改进措施。结果表明：上述问题是由半再生重整催化剂SR-1000氮中毒所引起的，通过采取控制原料馏程，更换新型缓蚀剂，提高预加氢反应器压力，调整蒸发塔和分馏塔操作等措施，可使重整装置汽油辛烷值增至97.5，循环氢中C3，C4体积分数降至3.27%，氢气纯度降至81%。
- Abstract:
- The problem of gasoline octane number and recycle gas C3， C4 content decreasing， elevated circulating hydrogen purity increasing in a 0.3 Mt/a reforming unit of Refinery & Chemical Plant of Yumen Oilfield Company，PetroChina， were analyzed， and the optimization measures were put forward. The results showed that the above problems were caused by semi-regeneration reforming catalyst SR-1000′s nitrogen poisoning. By adopting new measures such as controlling raw material distillation range， using new corrosion inhibitor， improving hydrogenation reactor pressure， adjusting evaporation tower and fractionating column measures， the gasoline octane number had increased to 97.5， circulating hydrogen C3， C4 volume fraction and hydrogen purity had decreased to 3.27%，81% respectively.
参考文献/References
［1］ 杨朝华，段超著.半再生催化重整催化剂SR-1000在玉门炼油厂的工业应用［J］.石油炼制与化工.2020，51（10）：77-80.［2］ 徐洪君，张海峰.半再生催化重整催化剂SR-1000首次工业应用［J］.石油炼制与化工，2019，50（11）：40-44.［3］ 王嘉欣，姜石.重整催化剂SR-1000在哈萨克斯坦炼油厂的应用［J］.石油炼制与化工，2020，51（3）：27-31.［4］ 陈雷.加氢装置氯化铵结盐腐蚀工艺控制［J］.石油化工腐蚀与防护，2019，36（2）：22-25.［5］ 齐晓梅.加氢裂化装置换热器结盐原因分析［J］.石油炼制与化工，2015，46（3）：57-60．
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更新日期/Last Update:
2023-01-10